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Polymorphism in iodotris(tri-p-tolylphosphine)silver( I)

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dc.contributor.author Venter, Gertruida J. S.
dc.contributor.author Roodt, Andreas
dc.contributor.author Meijboom, Reinout
dc.date.accessioned 2012-11-09T18:31:08Z
dc.date.available 2012-11-09T18:31:08Z
dc.date.issued 2009
dc.identifier.citation Venter, G. J. S., Roodt, A. & Meijboom, R. 2009. Polymorphism in iodotris(tri-p-tolylphosphine)silver( I). Acta Crystallographica Section B, B65:182-188. en_US
dc.identifier.issn 0108-7681
dc.identifier.uri http://hdl.handle.net/10210/8163
dc.description.abstract The reaction of silver(I) iodide with tri(p-tolyl)phosphine in MeCN solution in 1:3 molar ratio yields a polymorph of the complex of the formula [AgI{P(4-MeC₆H₄)₃}₃], with the Ag atom in a distorted tetrahedral environment. A polymorphic structure of this complex (a) is compared with previously published crystal structures (b), determined at different temperatures. The two polymorphs are compared using r.m.s. overlay calculations as well as half-normal probability plots. en_US
dc.language.iso en en_US
dc.publisher International Union of Crystallography en_US
dc.rights © International Union of Crystallography. 2009. Available online at http://journals.iucr.org/. DOI: 10.1107/S0108768109001372 en_US
dc.subject Silver phosphine complexes en_US
dc.subject Crystallography en_US
dc.title Polymorphism in iodotris(tri-p-tolylphosphine)silver( I) en_US
dc.type Article en_US


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